Shortwave Radio lacks readily avilable documentation, changes more frequently than AM/FM, and requires a number of different antennas to get the best reception. Setting all apprehensions aside I compiled a list, and found that most of the band is filled with evangelization, Spanish/Portuguese talk, and the occasional European station trying too hard.

Here is the list (Last Updated May 23rd 2010):

5.75 Mhz - ✝
5.90 Mhz - ✝
5.95 Mhz - ✝ (Bible Voice)
6.06 Mhz - Spanish
6.10 Mhz - ✝ (Soul Music)
6.18 Mhz - Spanish
6.50 Mhz - Digital Stream
7.00 Mhz - ✝ (Classic/Organ Music)
7.04 Mhz - CW Morse
7.41 Mhz - Day
7.45 Mhz - ✝
7.57 Mhz - ✝
8.41 Mhz - ✝
8.47 Mhz - ✝
8.50 Mhz - Russian Station (English Hit Music)
8.56 Mhz - ✝
8.60 Mhz - Francophone
8.65 Mhz - Powerful Chinese @ Night (Spanish Daytime)
8.68 Mhz - EuroTalk
8.75 Mhz - Voice of Russia
9.40 Mhz - ✝ (Bible Voice)
9.47 Mhz - ✝ (Scriptures for America, Colorado)
9.51 Mhz - RCI Fracophone (9800 drm)
9.63 Mhz - CBC Nord Quebec (Talk/News 9625)
10.65 Mhz - Spanish (Family Radio, Oakland California)
10.80 Mhz - ✝
10.85 Mhz - Spanish
11.00 Mhz - (WEAK)
11.01 Mhz - Spanish
11.55 Mhz - Spanish
11.60 Mhz - Spanish
11.75 Mhz - ✝
11.85 Mhz - Spanish
12.05 Mhz - Spanish (Politics)